Stereoselective stilbene epoxidation over supported gold-based catalysts |
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| Authors: | Lignier Pascal Morfin Franck Mangematin Stéphane Massin Laurence Rousset Jean-Luc Caps Valérie |
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| Institution: | Institut de Recherches sur la Catalyse (CNRS), 2 avenue Albert Einstein, 69626 Villeurbanne Cedex, France. |
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| Abstract: | The gold reference catalyst Au/TiO(2) exhibits high activity in the stereoselective epoxidation of trans-stilbene in methylcyclohexane in the presence of 5 mol% TBHP, by taking part in a chain reaction involving the activation of molecular oxygen by a radical produced from methylcyclohexane. |
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