Polymerization Behaviour of Organically Modified Titanium Alkoxides in Solution |
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Authors: | Gbureck Uwe Probst Jörn Thull Roger |
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Affiliation: | (1) Dept. of Functional Materials in Medicine & Dentistry, ZMK-Clinic, University of Wurzburg, Pleicherwall 2, Wurzburg, Germany, D-97070 |
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Abstract: | Modified titanium alkoxides with polymerizable organic ligands allow the synthesis of copolymers consisting of hybrid organic/inorganic networks. In this work titanium based-precursors were characterized in relation to the polymerization behaviour of the organic matrix. Alkoxide sols were prepared by reaction of methacrylic acid, itaconic acid anhydride, isoeugenol, p-vinylbezoic acid, p-vinylphenylacetic acid, and acetoxyacetomethacrylate with titanium tetraisopropoxide and titanium tetraethoxide. Polymerization reactions were carried out in solution using UV-irradiation and a redox-system of dibenzoylperoxide/N, N-dimethyl-p-toluidine as radical initiators. Especially for chemical activation some complexes showed high reactivity similar to silica-based methacrylates. The systems investigated are capable of acting as adhesive promoters between metal and polymer in dental applications. |
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Keywords: | titanium alkoxides polymerizable ligands UV-irradiation redox-polymerization FT-Raman spectroscopy |
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