| 铜胺络合物作用下取代2-萘酚的交叉偶合反应 |
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| 引用本文： | 王秀珍,庞冀燕,汪波,许遵乐. 铜胺络合物作用下取代2-萘酚的交叉偶合反应[J]. 有机化学, 2005, 25(7): 859-861 |
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| 作者姓名： | 王秀珍 庞冀燕 汪波 许遵乐 |
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| 作者单位： | 中山大学化学与化学工程学院,广州,510275 |
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| 摘 要： | 在铜(II)-胺络合物作用下, 取代2-萘酚化合物进行交叉偶合反应, 得到几种结构新颖的取代1,1'-联-2-萘酚化合物, 产率44%～90%. 化合物的结构经过核磁、红外光谱及质谱进行确证.
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| 关 键 词： | 取代1,1'-联-2-萘酚 铜胺络合物 氧化偶合反应 合成 |
| 收稿时间： | 2004-08-23 |
| 修稿时间： | 2004-01-18 |
Study on Cross-coupling Reactions of Substituted 2-Naphthols Promosted by Copper(II)-amine Complex |
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| WANG Xiu-zhen,PANG Ji-Yan,WANG Bo,XU Zun-Le. Study on Cross-coupling Reactions of Substituted 2-Naphthols Promosted by Copper(II)-amine Complex[J]. Chinese Journal of Organic Chemistry, 2005, 25(7): 859-861 |
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| Authors: | WANG Xiu-zhen PANG Ji-Yan WANG Bo XU Zun-Le |
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| Affiliation: | (School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275) |
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| Abstract: | The cross-coupling reaction of substituted 2-naphthols in the presence of copper(II)-amine complex was described. Several novel asymmetrically substituted bi-naphthol compounds were obtained in yields of 44%～90%. The structures of these compounds were characterized by 1H NMR, IR and FAB-MS spectra. |
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| Keywords: | substituted 1 1'-bi-2-naphthol copper-amine complex coupling reaction synthesis |
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