The molecular structure of tetrathiofulvalene-13C (TTF) from proton magnetic resonance studies using nematic solvents期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

The molecular structure of tetrathiofulvalene-13C (TTF) from proton magnetic resonance studies using nematic solvents

Authors:	T.C. Wong E.E. Burnell L. Weiler

Affiliation:	Department of Chemistry, Tufts University, Medford, Massachusetts 02155, USA;Department of Chemistry, University of British Columbia, Vancouver, Canada V6T 1W5

Abstract:	The molecular structure of TTF dissolved in nematic liquid crystalline solvents has been determined from the proton magnetic resonance including couplings due to ¹³C in natural abundance. The molecule is puckered in a boat conformation with the SCHCHS planes making a dihedral angle of 13 ± 2° with the S₂C  CS₂ plane. The other structural parameters obtained are r_CH = 1.085 ± 0.014 Å and the angel CCH = 123.7 ± 1.5°.

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