Resonant Raman spectroscopic study of biphenyl glutarate diacetylene polymer |
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Authors: | D. Bloor W. Hersel D.N. Batchelder |
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Affiliation: | Physikalisches Institut der Universität Stuttgart, Teil 3, 7000 Stuttgart-Vaihingen, 80, West-Germany;Department of Physics, Queen Mary College, London E1 4NS, UK |
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Abstract: | The resonantly enhanced Raman spectra of biphenyl glutarate diacetylene polymer chains in fully radiation polymerized and partially thermally polymerized samples are reported. Details of the resonant enhancement in the region of the polymer electronic absorption were studied in partially polymerized samples. The role of defects in producing fluorescent emission and in broadening the optical absorption for radiation polymerized samples is briefly discussed. |
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