Deactivation of vibrationally excited CD3H using laser-induced fluorescence |
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| Authors: | Walter S Drozdoski Asghar Fakhr Richard D Bates |
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| Institution: | Department of Chemistry, Georgetown University, Washington, D.C. 20057, USA |
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| Abstract: | Infrared fluorescence observed after exciting to ν6 (ν=1) of CD3H with a Q-switched CO2 laser yields the exponential deactivation rate constant of 0.84 ms?1 torr?1. Rate constants for deactivation of CD3H by rare gases vary from 1.4 (for He) to 0.029 (for Xe) ms?1 torr?1. |
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