Comparison between infrared and raman band profiles in the absence of rotational relaxation in the liquid phase: ν(OH) of methanol in acetonitrile |
| |
| Authors: | Jean Limouzi André Burneau Jean Pierre Perchard |
| |
| Affiliation: | Laboratoire de Chimie Physique du CNRS, 94 Thiais, France;Laboratoire de Spectrochimie Moléculaire, Université Pierre et Marie Curie, 75230 Paris Cedex 05, France |
| |
| Abstract: | In the case of weakly hydrogen bonded systems OH…B it has been shown that the ν(OH) IR and Raman band profiles are not identical. The origin of this difference is discussed in terms of changes in the dipole moment and polarizability derivatives with intermolecular forces |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
