The photoelectron spectra of the OH and OD radicals |
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| Authors: | S Katsumata DR Lloyd |
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| Institution: | Chemistry Department, The University, Birmingham B15 2TT, UK |
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| Abstract: | He(I) photoelectron spectra of the hydroxyl radical show ionizations corresponding to the production of OH+ (OD+) in the states X 3Σ? and 1Δ at ionization potentials of 13.01 eV and 15.20 eV respectively. The excitation energy of the 1Δ state is in very good agreement with that predicted by calculation and experiment; vibrational spacings in the X 3Σ? state agree with emission spectroscopic data. |
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