Synthesis of (+)-uniflorine a: a structural reassignment and a configurational assignment |
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| Authors: | Ritthiwigrom Thunwadee Pyne Stephen G |
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| Affiliation: | School of Chemistry, University of Wollongong, Wollongong, New South Wales 2522, Australia. |
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| Abstract: | The total synthesis of (+)-uniflorine A has allowed for the structural reassignment and the configurational assignment of the alkaloid (-)-uniflorine A from a 1,2,6,7,8-pentahydroxyindolizidine structure to (-)-(1 R,2 R,3 R,6 R,7 S,7a R)-1,2,6,7-tetrahydroxy-3-hydroxymethylpyrrolizidine (6- epi-casuarine). |
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