| 掺杂Tb3+的混合碱土金属钨酸盐的合成和性质 |
| |
| 引用本文： | 杨水金,孙聚堂,秦子斌,冯伊利.掺杂Tb3+的混合碱土金属钨酸盐的合成和性质[J].无机化学学报,1994,10(4):358-362. |
| |
| 作者姓名： | 杨水金 孙聚堂 秦子斌 冯伊利 |
| |
| 作者单位： | 武汉大学化学系，青海教育学院化学系 |
| |
| 摘 要： | 合成了掺杂Ｔｂ（３＋）的混合碱土金属钨酸盐，测定了其发射光谱和激发光谱，用粉末Ｘ射线衍射和电子衍射法表征了其晶体结构，并对钨酸钙钡单晶体进行了Ｘ射线能谱成份分析．探讨了碱土金属钨酸盐的溶混性成因以及在这些晶体中Ｔｂ（３＋）发光和能量传递机理．
|
| 关 键 词： | 锑 碱土金属 钨酸盐 合成 发光 能量传递 |
| 收稿时间： | 1993/10/31 0:00:00 |
SYNTHESIS AND PROPERTIES OF Tb3+-DOPED MIXED ALKALI-EARTH METAL TUNGSTATES |
| |
| Yang Shuijin,Sun Jutang,Qin Zibin and Feng Yili.SYNTHESIS AND PROPERTIES OF Tb3+-DOPED MIXED ALKALI-EARTH METAL TUNGSTATES[J].Chinese Journal of Inorganic Chemistry,1994,10(4):358-362. |
| |
| Authors: | Yang Shuijin Sun Jutang Qin Zibin and Feng Yili |
| |
| Abstract: | he Tb(3+)-doped CaSr(WO4)2, SrBa (WO4)2 and (Ca(1-x)Bax)WO4 have been synthesized.The emission and excitation spectra were measured. The crystal structures were studied by means of powder X-ray diffraction and single crystal electron diffraction methods.The compositions of (Ca(1-x)Bax)WO4 were analyzed with X-ray energy dispersive spectromcter(EDS).The miscibility of alkali-earth metal tungstates,and the luminescence of Tb(3+)ion and energy transfer mechanism were discussed. |
| |
| Keywords: | alkali-earth metal tungstate miscibility luminescence |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
