| Me[14]-N4大环四烯镍(Ⅱ)催化、BrO3-氧化丙酮酸的振荡化学反 |
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| 引用本文： | 许志强,谢复新,杨光,倪诗圣.Me[14]-N4大环四烯镍(Ⅱ)催化、BrO3-氧化丙酮酸的振荡化学反[J].无机化学学报,1994,10(1):75-79. |
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| 作者姓名： | 许志强 谢复新 杨光 倪诗圣 |
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| 作者单位： | 安徽大学化学系, 合肥, 230039;南京大学配位化学国家重点实验室, 南京, 210008,安徽大学化学系, 合肥, 230039;南京大学配位化学国家重点实验室, 南京, 210008,安徽大学化学系, 合肥, 230039;南京大学配位化学国家重点实验室, 南京, 210008,安徽大学化学系, 合肥, 230039;南京大学配位化学国家重点实验室, 南京, 210008 |
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| 摘 要： | 本文报道了一种以２，３，９，１０－四甲基－１，４，８，１１－四氮杂环十四－１，３，８，１０－四烯镍（Ⅱ）配合物［Ｎｉ（ㄔＩＭ）］＾２＋为催化剂、ＮａＢｒＯ３为氧化剂、丙酮酸为有机废物、稀硫酸为介质的振荡化学反应新体系。对该体系的振荡特性进行了描述。研究了Ａｇ＾＋、Ｈｇ＾２＋、还原性物质、自由基抑制剂、四氯化碳以及温度对振荡的影响。
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| 关 键 词： | 四氮杂大环 镍络合物 振荡 丙酮酸 |
| 收稿时间： | 1993/2/15 0:00:00 |
STUDY ON THE NEW OSCILLATING REACTIONS CATALYZED BY TIM AND PYRUVIC ACID AS SUBSTRATE |
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| Xu Zhiqiang,Xie Fuxin,Yang Guang and Ni Shisheng.STUDY ON THE NEW OSCILLATING REACTIONS CATALYZED BY TIM AND PYRUVIC ACID AS SUBSTRATE[J].Chinese Journal of Inorganic Chemistry,1994,10(1):75-79. |
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| Authors: | Xu Zhiqiang Xie Fuxin Yang Guang and Ni Shisheng |
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| Institution: | Department of Chemistry, Anhui University, Hefei, 230039;National Key laboratory of Coordination Chemistry, Nanjing Uaiversity, Nanjing, 210008,Department of Chemistry, Anhui University, Hefei, 230039;National Key laboratory of Coordination Chemistry, Nanjing Uaiversity, Nanjing, 210008,Department of Chemistry, Anhui University, Hefei, 230039;National Key laboratory of Coordination Chemistry, Nanjing Uaiversity, Nanjing, 210008 and Department of Chemistry, Anhui University, Hefei, 230039;National Key laboratory of Coordination Chemistry, Nanjing Uaiversity, Nanjing, 210008 |
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| Abstract: | In this paper. we reported a new kind of oscillating chemical reactions in the system of NaBrO3-pyruvic acid-H2SO4Ni(TIM)](CIO4)2. where TIM is 2,3,9,10-tetramethyl-1,4,8,11-tetraazacyotetradeca-1,4,8,11-tetraene. The feature s of the oscillations were describedin detail. We have studied the effects of Ag, Hg, CCI4. reductants, radical imhibitors, and temperature on the oscillations. |
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| Keywords: | tetraazamacrocyclic nickel complex escillating chemical reaction pyruvic acid |
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