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Adsorptive stripping voltammetry of some trace elements in biological samples,II: Nickel,arsenic, aluminium and selenium
Authors:Li Chiang  Bruce D James  Robert J Magee
Institution:(1) Department of Chemistry, La Trobe University, 3083 Bundoora, Melbourne, Victoria, Australia
Abstract:A study of the adsorptive stripping voltammetry of nickel, aluminium, selenium and arsenic is reported in which 2,5-dimercapto-1,3,4-thiadiazole (DMTD) has been used as a chelating agent. By a suitable choice of deposition potential, deposition time, reagent reaction time and other operating conditions, the determination of the four elements could be achieved.By the use of benzyltrimethyl ammonium methoxide as a digesting solvent, it was possible to apply the procedure to the direct determination of the four elements in biological samples.
Keywords:adsorptive stripping voltammetry  nickel  aluminium  selenium  arsenic
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