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New high-pressures vapor-liquid equilibrium data for the carbon dioxide + 2-methyl-2-propanol binary system |
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| Authors: | Sergiu?Sima,Catinca?Secuianu author-information" > author-information__contact u-icon-before" > mailto:c_secuianu@chim.upb.ro" title=" c_secuianu@chim.upb.ro" itemprop=" email" data-track=" click" data-track-action=" Email author" data-track-label=" " >Email author,Viorel?Feroiu,Dan?Gean? | |
| Affiliation: | 1.Department of Inorganic Chemistry, Physical Chemistry & Electrochemistry,University Politehnica of Bucharest, S1,Bucharest,Romania;2.Department of Chemical Engineering,Imperial College London, South Kensington Campus,London,Uk | |
| Abstract: | New vapor-liquid equilibria (VLE) data at 323.15, 333.15, 343.15, and 353.15 K and pressures up to 112.9 bar are reported for the carbon dioxide + 2-methyl-2-propanol system. The experimental method used in this work was a static analytical method with liquid and vapor phases sampling using a rapid online sampler injector (ROLSI?) coupled to a gas chromatograph (GC) for analysis. Measured VLE data and literature data for carbon dioxide + 2-methyl-2-propanol system were modeled with the Soave-Redlich-Kwong (SRK) cubic equation of state with classical van der Waals (two-parameter conventional mixing rule, 2PCMR) mixing rules. A single set of interaction parameters that lead to a correct phase behavior was used in this work to model the new VLE data and critical points of the mixtures in a wide range of temperature and pressure. The SRK prediction results were compared to the new data measured in this study and to available literature data. | |
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