Pyridino-18-crown-6 ether type chemosensors containing a benzothiazole fluorophore unit: Synthesis and enantiomeric recognition studies |
| |
| Authors: | Dávid Pál Ildikó Móczár Balázs Szemenyei Dániel Marczona Ivett Kocsis Gergely Prikler Panna Vezse Péter Baranyai Péter Huszthy |
| |
| Institution: | 1. Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, PO Box 91, H-1521, Budapest, Hungary;2. Department of Applied and Nonlinear Optics, Institute of Solid State Physics and Optics, Wigner Research Center for Physics, Hungarian Academy of Sciences, PO Box 49, H-1525, Budapest, Hungary |
| |
| Abstract: | Three new fluorescent enantiopure pyridino-18-crown-6 ethers containing a benzothiazole unit were prepared, and the enantiomeric discrimination of these sensor molecules toward the hydrogen perchlorate salts of 1-phenylethylamine, 1-(1-naphthyl)ethylamine, phenylglycine methyl ester and phenylalanine methyl ester was studied in acetonitrile by fluorescence spectroscopy. The ligands revealed appreciable or moderate selectivity toward the enantiomers of hydrogen perchlorate salts of 1-phenylethylamine, 1-(1-naphthyl)ethylamine and phenylglycine methyl ester. |
| |
| Keywords: | Pyridino-crown ether Complexation Enantiomeric recognition Benzothiazole Fluorescent sensor molecule |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
