Investigation of binuclear metal phthalocyanines as electrocatalysts for Li/SOCl<Subscript>2</Subscript> battery期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Investigation of binuclear metal phthalocyanines as electrocatalysts for Li/SOCl2 battery

Authors:	Bei?Xu,RongLan?Zhang author-information" > author-information__contact u-icon-before" > mailto:sdzrl@.com" title=" sdzrl@.com" itemprop=" email" data-track=" click" data-track-action=" Email author" data-track-label=" " >Email author,JiFeng?Wang,JianShe?Zhao author-information" > author-information__contact u-icon-before" > mailto:jszhao@nwu.edu.cn" title=" jszhao@nwu.edu.cn" itemprop=" email" data-track=" click" data-track-action=" Email author" data-track-label=" " >Email author

Affiliation:	1.Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science,Northwest University,Xi’an,China

Abstract:	Three novel series of the binuclear metal phthalocyanines M₂Pc₂, M₂Pc₂Hc, and M₂Nc₂ (M?=?Mn(II), Fe(II), Co(II), Ni(II), and Cu(II)) were synthesized and characterized. The electrocatalytic performance of the binuclear compounds to lithium–thionyl chloride battery was evaluated by operating these compounds in the electrolyte of the battery. The results indicated that the binuclear metal phthalocyanines improved the capacity of the battery by an increase of approximately 30–58 %. Of all, Cu₂Pc₂Hc and Fe₂Nc₂ displayed the highest increments of 56 and 57 %, respectively.

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