Rheological properties of polymer blends with sphere-in-sphere morphology |
| |
Authors: | Michael Fahrländer Christian Friedrich |
| |
Institution: | Freiburger Materialforschungszentrum FMF and Institut für Makromolekulare Chemie Hermann-Staudinger-Haus Albert-Ludwigs-Universit?t Stefan-Meier-Strasse 21, D-79104 Freiburg im Breisgau, Germany e-mail: chf@fmf.uni-freiburg.de, DE
|
| |
Abstract: | The linear viscoelastic behavior of polystyrene (PS) and poly(methylmethacrylate) (PMMA) blends with PS as the matrix and
amounts of PMMA in the range 10–30 wt% was investigated. Transmission electron microscopy (TEM) revealed a complex morphology
which was characterized by the existence of composite particles; the PMMA particles which are enclosed in the PS matrix themselves
carry PS inclusions. In order to explain the G* data of these blends a model is presented which consists of a Palierne model for the composite particles and a Palierne
model for the whole blend, taking into account composite and neat particles. Simulations show the principal relevance of the
assumptions made. Moreover, it is shown that the measurements agree well with the model for the whole measured frequency region
and that the fit parameters, the size of the composite particles and the concentration and size of interior particles are
in reasonable agreement with data available from TEM.
Received: 1 November 1998 Accepted: 5 April 1999 |
| |
Keywords: | Polymer blends Morphology Composite particles Palierne model Complex modulus |
本文献已被 SpringerLink 等数据库收录! |