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Optical Properties of Metacycline, Oxytetracycline and Chlortetracycline Europium Complexes in the Presence of Hydrogen Peroxide
Authors:Andrea Nastri Grasso  Luciane dos Santos Teixeira  Nilson Dias Vieira Jr.  Lilia Coronato Courrol
Affiliation:1. Centro de Lasers e Aplica??es, IPEN/CNEN-SP, Av. Lineu Prestes 2242 - Cidade Universitária, S?o Paulo, SP, Brazil
2. Departamento de Ciências Exatas e da Terra, Universidade Federal de S?o Paulo—UNIFESP, Campus Diadema, Rua Prof. Artur Riedel, 275, Bairro Jd, Eldorado—Diadema, S?o Paulo, Brazil, 09972-270
Abstract:Tetracycline possesses a great tendency to form complexes with a number of chemical species, particularly with Eu3+ ions. In this work we investigate the europium optical properties of three tetracyclines europium complexes: Metacycline (MTc), Oxytetracycline (OTc), and Chlortetracycline (CTc), in the presence and absence of hydrogen peroxide (HP). The results show that the emission band of EuOTc have enhancement in the presence of hydrogen peroxide. A calibration curve was shown for this complex with the best molar ratio obtained.
Keywords:Spectroscopy  Fluorescence  Lanthanides complexes  Hydrogen peroxide
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