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Upconversion emission in Er3+-doped lead niobium germanate thin-film glasses produced by pulsed laser deposition
Authors:F. Lahoz  P. Haro-Gonzalez  F. Rivera-López  S. González-Pérez  I. R. Martín  N. E. Capuj  C. N. Afonso  J. Gonzalo  J. Fernández  R. Balda
Affiliation:(1) Departamento de Física Fundamental y Experimental, Eléctronica y Sistemas, University of La Laguna, 38206 La Laguna, Tenerife, Spain;(2) Departamento de Física Básica, University of La Laguna, 38206 La Laguna, Tenerife, Spain;(3) Laser Processing Group, Instituto de Optica, CSIC, Serrano 121, 28006 Madrid, Spain;(4) Departamento de Fisica Aplicada I, Escuela Superior de Ingenieros, Alda. Urquijo s/n, 48013 Bilbao, Spain;(5) Centro Mixto CSIC-UPV/EHU and DIPC, Donostia, Spain
Abstract:Thin films of Er3+-doped lead–niobium germanate have been produced by pulsed laser deposition from Er3+-doped 25PbO2–25Nb2O5–50GeO2 (mol%) transparent glasses with an Er content in the range 0.5–3 wt%. The room-temperature infrared to visible upconversion properties of these thin films have been investigated under 800-nm laser excitation. An energy transfer upconversion mechanism has been identified to be responsible for the population of the 4S3/2:2H11/2 excited level, from which an intense green emission occurs. A rate equation analysis supports the proposed mechanism.
Keywords:  KeywordHeading"  >PACS 78.20.-e  78.47.Cd  78.55.Qr  78.66.Jg
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