Luminescent properties of new naphthylnitroxyl radicals |
| |
Authors: | A. G. Matveeva E. M. Glebov V. V. Korolev I. P. Pozdnyakov V. F. Plyusnin D. V. Stass V. A. Reznikov |
| |
Affiliation: | 1.Institute of Chemical Kinetics and Combustion,Siberian Branch of the Russian Academy of Sciences,Novosibirsk,Russian Federation;2.N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry,Siberian Branch of the Russian Academy of Sciences,Novosibirsk,Russian Federation;3.Novisibirsk State University,Novosibirsk,Russian Federation |
| |
Abstract: | Method of time-resolved fluorescence was applied to study the luminescent properties of several 3-and 2-imidazoline derivatives of naphthalene. For 2-imidazoline derivatives in which the imidazoline fragment is directly bound to the naphthalene fragment, a weak (quantum yield φ < 0.001) luminescence of common π-system containing the radical group and the naphthalene core was recorded. 3-imidazoline derivatives, in which naphthalene and imidazoline fragments are separated by an ethylene bridge, demonstrate luminescence with the spectrum similar to that of free naphthalene. Quantum yield of luminescence and life-time of singlet excited state of 3-imidazoline derivatives are ca. 50 times less than for free naphthalene, because of intramolecular quenching of the luminophore luminescence by a stable radical. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|