双-[N(4-取代苯基)-水杨醛亚胺]合锌(Ⅱ)的晶体结构

为进一步研究过渡金属离子与席夫碱配合和的结构与性能的关系,本文报道双-N-(4-取代苯基)-水杨醛亚胺]合锌的晶体结构.

Crystal structures of [N-(4-substituted-phenyl)-salicylaldiminato]zn(Ⅱ)

The crystal structures of bis(N-phenylsalicylaldiminato)zinc (I) and bis(N-(4-methylphenyl)salicylaldiminato)zinc (II) were determine I is triclinic, space group P1, with a 0.9433(4), b 1.0703(3), c 1.2217(4) nm, a 68.05(2), b 68.15(2), and g 78.28(3)? Z = 2, dc = 1.436; R = 0.080, Rw = 0.067. II is orthorhombic, space group Pbca, with a 1.0863(2), b 1.7575(7), and c 2.4065(6) nm; Z = 8, dc = 1.405; R = 0.043, Rw = 0.048. Atomic coordinates, bond distances and angles are given.