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Comparative Mössbauer study of EuBa2 (Cu1-x 57Fe x )3O7-d and EuBa2Cu1-x 57Fe x )4O8 superconductors
Authors:E. Kuzmann  S. Nagy  M. Gál  G. K. Sólymos  Z. Homonnay  A. Vértes  B. Csákvári  J. Bánkuti  I. Kirschner
Affiliation:1. Department of Nuclear Chemistry, E?tv?s University, Budapest, Hungary
2. Department of General and Inorganic Chemistry, E?tv?s University, Budapest, Hungary
3. Department of Low Temperature Physics, E?tv?s University, Budapest, Hungary
Abstract:Structural differences between the 1-2-3 type and 1-2-4 type high temperature superconductors were studied by comparing their151Eu and57Fe Mössbauer spectra. The similarities between the corresponding Mössbauer parameters of Eu Mössbauer spectra of 1-2-3 and 1-2-4 compounds demonstrate that the Eu state can be considered to be identical in both perovskites. The changes in the Fe Mössbauer parameters of 1-2-4 type superconductor compared to those of 1-2-3 type compound can be associated with structural differences.
Keywords:
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