Photodissociation of aromatic thiols and disulfides |
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Authors: | N A Borisevich Ya N Malkin Sh Ruziev S V Mel'nichuk S A Tikhomirov G B Tolstorozhev V A Kuz'min |
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Institution: | (1) N. N.Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow;(2) Institute of Physics, Academy of Sciences of the Belorussian SSR, Minsk |
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Abstract: | For the first time, the quantum yields of cleavage of SS and SH bonds in a disulfide and a thiol and also the extinction coefficient of the photoinduced aminophenylthiyl radical were determined, on the basis of which the relation of the photodissociation quantum yield to the energy of an absorbed quantum was observed.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 540–543, March, 1990. |
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