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Room temperature rate coefficient for the reaction between CH3O2 and NO3 |
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| Authors: | J N Crowley J P Burrows G K Moortgat G Poulet G LeBras |
| Abstract: | The molecular modulation spectroscopic technique was employed to study the kinetics of NO3 radicals produced in the 253.7 nm photolysis of flowing gas mixtures of HNO3/CH4/O2 at room temperature. By computer fitting of the NO3 temporal behavior, a rate coefficient of (2.3 ± 0.7) × 10?12 cm3 molecule?1 s?1 was obtained for the reaction between NO3 and CH3O2 at 298 K. |
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