首页 | 本学科首页   官方微博 | 高级检索  
     检索      


Rate constants for the reactions of OH radicals and Cl atoms with diethyl sulfide,Di-n-propyl sulfide,and Di-n-butyl sulfide
Authors:Ole J Nielsen  Howard W Sidebottom  Linda Nelson  Oliver Rattigan  Jack J Treacy  Denis J O'Farrell
Abstract:Rate constants for the reactions of OH radicals and Cl atoms with diethyl sulfide (DES), di-n-propyl sulfide (DPS), and di-n-butyl sulfide (DBS) have been determined at 295 ± 3 K and a total pressure of 1 atm. Hydroxyl radical rate data was obtained using the absolute technique of pulse radiolysis combined with kinetic spectroscopy. The chlorine atom rate constants were measured using a conventional photolytic relative rate method. The rate constant for the reaction of Cl atoms with dimethyl sulfide (DMS) was also determined. The following rate constants were obtained: equation image
Keywords:
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号