Abstract: | New Metallatranes of Transition Elements: Chloro- and Cyclopentadienyltitatrane and Chloro- and Acetatozirconatrane Synthesis and characterization of chloro- and cyclopentadienyltitatrane, ClTi(OCH2CH2)3N]2 and CpTi(OCH2CH2)3N], and of chloro- and acetatozirconatrane, ClZr(OCH2CH2)3N]n and CH3CO2Zr(OCH2CH2)3N]2, as well are described as new types of metallatranes of transition elements. |