Darstellung von Dichlornitronium-hexafluoroarsenat und -hexafluoroantimonat ONCl2+MF6−(M = As,Sb) |
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| Authors: | R Minkwitz D Bernstein W Sawodny H Hrtner |
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| Institution: | R. Minkwitz,D. Bernstein,W. Sawodny,H. Härtner |
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| Abstract: | Preparation of Dichlornitronium-hexafluoroarsenate and -hexafluoroantimonate ONCl2+MF6?(M = As, Sb) The preparation of ONCl2+MF6? (M = As, Sb) by oxidative chlorination of CNCl with Cl2/AsF5 and Cl2/SbF5 is reported. Both salts are characterized by Raman Spectroscopy. The difficulties in evaluating a force field for the cation are discussed. |
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