| 四（3,4-亚甲二氧基苯基）卟啉的合成及光谱分析 |
| |
| 引用本文： | 吕艳阳,韩静,李娟,张小雨. 四（3,4-亚甲二氧基苯基）卟啉的合成及光谱分析[J]. 光谱实验室, 2011, 28(3): 1215-1218 |
| |
| 作者姓名： | 吕艳阳 韩静 李娟 张小雨 |
| |
| 作者单位： | 1. 信阳师范学院化学化工学院,河南省信阳市长安路237号,464000
2. 河南省濮阳油田第三高级中学,河南省濮阳市五一路,457001 |
| |
| 基金项目： | 河南省教育厅自然科学基金项目(2008A150021) |
| |
| 摘 要： | 研究了以3,4-亚甲二氧基苯甲醛和吡咯为原料合成四（3,4-亚甲二氧基苯基）卟啉的方法,探索了溶剂、催化剂等反应条件对合成的影响。新化合物结构分别被UV-Vis,IR,1H NMR及元素分析所证实。利用紫外-可见分光光度法和荧光光谱法研究了四（3,4-亚甲二氧基苯基）卟啉在四氢呋喃（THF）、丙酮、氯仿、N,N-二甲基甲酰胺（DMF）4种溶剂中的光谱性质。
|
| 关 键 词： | 四（3,4-亚甲二氧基苯基）卟啉 合成 光谱分析 |
Synthesis and Spectral Analysis of Tetra(3,4-Methylenedioxy Benzaldehyde)Porphyrin |
| |
| LV Yan-Yang HAN Jinga LI Juan ZHANG Xiao-Yua. Synthesis and Spectral Analysis of Tetra(3,4-Methylenedioxy Benzaldehyde)Porphyrin[J]. Chinese Journal of Spectroscopy Laboratory, 2011, 28(3): 1215-1218 |
| |
| Authors: | LV Yan-Yang HAN Jinga LI Juan ZHANG Xiao-Yua |
| |
| Affiliation: | LV Yan-Yang HAN Jinga LI Juan ZHANG Xiao-Yu(College of Chemistry and Chemical Engineering,Xinyang Normal University,Xinyang,Henan 464000,P.R.China)a(3rd High School in Puyang Oil Field in Henan,Puyang,Henan 457001,P.R.China) |
| |
| Abstract: | A new tetra(3,4-methylenedioxy benzaldehyde) porphyrin was synthesized with 3,4-methylenedioxy benzaldehyde and porphyrin as raw material.Influences of the reaction condition such as solvent and catalyst were explored.Its structure was confirmed by UV-Vis,IR,1H NMR and elemental analysis.Its spectral properties in four kinds of solvents,including tetrahydrofuran(THF),acetone,chloroform,N,N-dimethylformamide(DMF),were studied by UV-Vis spectrophotometry and fluorescence spectrometry. |
| |
| Keywords: | Tetra(3 4-Methylenedioxy Benzaldehyde) Porphyrin Synthesis Spectral Analysis |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
