| Efficient Synthesis of the C1-C7 Fragment of Didemnaketal A |
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| 作者姓名： | XueQiangLI XueZhiZHAO PeiNianLIU YongQiangTU |
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| 作者单位： | DepartmentofChemistryandStateKeyLaboratoryofAppliedOrganicChemistry,LanzhouUniversity,Lanzhou730000 |
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| 摘 要： | The stereoselective synthesis of the CI-C7 fragment (3R,4S,6R)-3,4-di(tert-butyldimethylsilyl)oxy]-7-hydroxy-6-methylheptan-2-one, which is the crucial intermediate for synthesis ofthe HIV-1 protease inhibitive didemnaketals, was developed via 12 steps from the natural ( )-pulegone.
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| 关 键 词： | 立体选择性合成 分子内部手性感应 Mitsunobu反应 C1-C7碳水化合物 天然产物 Didemnaketal A |
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