Crystal structure of a nickel(II) complex with macrocyclic tetraamine |
| |
| Authors: | Jun Li Yan-Wei Ren Jin-Hua Zhang Pin Yang |
| |
| Institution: | (1) Institute of Molecular Science, Shanxi University, Taiyuan, 030006, People's Republic of China;(2) Chemistry Department, Northwest University, Xi'an, 710069, People's Republic of China |
| |
| Abstract: | A new compound Ni(cyclen)( 2-CH3CO2)]BF4 (cyclen = 1,4,7,10-tetraazacyclodode- cane) has been synthesized and characterized structurally. It crystallizes in the orthorhombic system, space group Pnnm with a =12.045(5), b =14.906(6), c =8.913(4) Å, V =1600.4(12) Å3, and Z =4. The nickel(II) ion has a distorted octahedral geometry with four secondary amines of the macrocycle and two oxygen atoms of the bidentate acetate group. TGA curve shows its thermal stability is up to 280°C. |
| |
| Keywords: | Crystal structure nickel(II) complex macrocycle acetate group |
| 本文献已被 SpringerLink 等数据库收录！ |
|
