Noncyclic [10-S-5] sulfuranide dioxide salts with three S-C bonds: a new class of stable hypervalent compounds |
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| Authors: | Sevenard Dmitri V Kolomeitsev Alexander A Hoge Berthold Lork Enno Röschenthaler Gerd-Volker |
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| Affiliation: | Institute of Inorganic & Physical Chemistry, University of Bremen, Leobener Strasse, 28334 Bremen, Germany. |
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| Abstract: | ![]()
Phenyl triflate reacts with CF3SiMe3/Q+F- (Q+ = [K(18-crown-6)]+, Me4N+) and (Me2N)3S+Me3SiF2- to afford the first noncyclic [10-S-5] sulfuranide dioxide salts, [(CF3)3SO2]-Q+, with three S-C bonds, whose molecular structure was determined by X-ray crystallography. |
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