Noncyclic [10-S-5] sulfuranide dioxide salts with three S-C bonds: a new class of stable hypervalent compounds |
| |
Authors: | Sevenard Dmitri V Kolomeitsev Alexander A Hoge Berthold Lork Enno Röschenthaler Gerd-Volker |
| |
Institution: | Institute of Inorganic & Physical Chemistry, University of Bremen, Leobener Strasse, 28334 Bremen, Germany. |
| |
Abstract: | Phenyl triflate reacts with CF3SiMe3/Q+F- (Q+ = K(18-crown-6)]+, Me4N+) and (Me2N)3S+Me3SiF2- to afford the first noncyclic 10-S-5] sulfuranide dioxide salts, (CF3)3SO2]-Q+, with three S-C bonds, whose molecular structure was determined by X-ray crystallography. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|