Synthesis of polyfluoroaromatic ketones from polyfluoroarylzinc compounds and acyl chlorides in the presence of CuCl |
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Authors: | A. S. Vinogradov V. I. Krasnov V. E. Platonov |
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Affiliation: | (1) Endocrine Oncology Program, Comprehensive Cancer Center, University of Michigan, 1500 East Medical Center Drive, Ann Arbor, MI 48109, USA |
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Abstract: | Polyfluoroaromatic ketones ArFCOAlk and ArFCOPh (ArF = C6F5, 3- and 4-F3CC6F4, 4-NCC6F4, 4-EtOCOC6F4, C5F4N, nonafluoroindan-5-yl; Alk = Me, Et, i-Pr, t-Bu) were synthesized by reactions of polyfluoroarylzinc compounds with acyl chlorides in the presence of CuCl. |
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