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Inhibition of Pb-Leaching from Lead Crystal Glass by Coating with Films Prepared by the Sol-Gel Method
Authors:A.A. Ahmed  I.M. Youssof  A.F. Abbas  O. Abou Eleinen
Affiliation:(1) Glass Research Laboratory, National Research Center, Dokki, Cairo, 12622, Egypt;(2) Petroleum Applications Department, Petroleum Research Institute, Nasr City, Cairo, Egypt
Abstract:The chemical durability of lead glass tumblers (24% PbO) in a 4% (v/v) acetic acid solution before and after coating with sol-gel derived SiO2 films was assessed to determine the extent of reduction in Pb-leaching that can be achieved. It was found that by coating the internal surface of the glass tumblers with 1 ml of 10% TEOS solutions at 100°C and densifying the coating formed at 500°C for 1 h, it was possible to reduce Pb-leaching to about one quarter of that of the uncoated glass.
Keywords:lead crystal glass  sol-gel coating  lead leaching  durability improvement
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