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Enhancing selectivity in oxidation catalysis with sol-gel nanocomposites
Authors:Gancitano Pamela  Ciriminna Rosaria  Testa Maria Luisa  Fidalgo Alexandra  Ilharco Laura M  Pagliaro Mario
Affiliation:Istituto per lo Studio dei Materiali Nanostrutturati, CNR, via U. La Malfa 153, 90146, Palermo, Italy.
Abstract:Valuable organic compounds such as alpha-hydroxy acids are easily synthesised with relevant selectivity enhancement using a sol-gel hydrophobized nanostructured silica matrix doped with the organocatalyst TEMPO: A materials science based synthetic route which cannot be achieved via classical homogeneous synthesis.
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