Nickel-catalyzed reactions of silacyclobutanes with aldehydes: ring opening and ring expansion reaction |
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| Authors: | Hirano Koji Yorimitsu Hideki Oshima Koichiro |
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| Institution: | Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan. |
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| Abstract: | reaction: see text]. The nickel-catalyzed ring opening reaction of silacyclobutanes with aldehydes affords the corresponding alkoxyallylsilanes. In contrast, the ring expansion reaction of benzosilacyclobutene with aldehydes occurs under nickel catalysis to give oxasilacyclohexenes. |
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