The Allylcobalt System |
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Authors: | Helmut Bnnemann Charles Grard Werner Kopp Wichard Pump Kenjiro Tanaka Günther Wilke |
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Institution: | Helmut Bönnemann,Charles Grard,Werner Kopp,Wichard Pump,Kenjiro Tanaka,Günther Wilke |
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Abstract: | The following report describes the preparation and reactions of organocobalt compounds, especially the thermally unstable tris(π-allyl)cobalt and cyclooctenylcobalt compounds. The stoichiometric and catalytic transformations of these highly reactive organocobalt systems give an insight into the rôle of cobalt in homogeneous catalysis involving alkenes and alkynes. |
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