Single-scan 2D DOSY NMR spectroscopy |
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Authors: | Shrot Yoav Frydman Lucio |
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Affiliation: | aDepartment of Chemical Physics, Weizmann Institute of Science, 76100 Rehovot, Israel |
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Abstract: | Spatial encoding is a particular kind of spin manipulation that enables the acquisition of multidimensional NMR spectra within a single scan. This encoding has been shown to possess a general applicability and to enable the completion of arbitrary nD NMR acquisitions within a single transient. The present study explores its potential towards the acquisition of 2D DOSY spectra, where the indirect dimension is meant to encode molecular displacements rather than a coherent spin evolution. We find that in its simplest form this extension shows similarities with methods that have been recently discussed for the single-scan acquisition of this kind of traces; still, a number of advantageous features are also evidenced by the “ultrafast” modality hereby introduced. The principles underlying the operation of this new single-scan 2D DOSY approach are discussed, its use is illustrated with a variety of sequences and of samples, the limitations of this new experiment are noted, and potential extensions of the methodology are mentioned. |
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Keywords: | 2D DOSY Ultrafast NMR Diffusion measurements New NMR techniques |
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