2,2';9',2'-Ter[1,10]phenanthroline |
| |
Authors: | Zong Ruifa Thummel Randolph P |
| |
Affiliation: | Department of Chemistry, 136 Fleming Building, University of Houston, Houston, Texas 77204-5003, USA. |
| |
Abstract: | The title molecule, 2,2';9',2'-ter[1,10]phenanthroline can be prepared from 2,9-dichloro-1,10-phenanthroline in three steps through the corresponding diacetyl intermediate. The ligand acts as a hexadentate with K+, while two molecules form a trinuclear, helical complex with Cu(I), which evidences pi-stacking interactions and Cu-Cu distances of 3.01-3.04 A. Electrochemical analysis shows a strong interaction between the Cu(I) centers. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|