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Stereochemistry of amino-carbonyl compounds—VII: Absolute and ralative configuration of some diastereomeric 1,3-amino-alcohols. |
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| Authors: | M Tramontini L Angiolini C Fouquey J Jacques |
| Institution: | aInstituto di Chimica degli Intermedi, Facolta´di Chimica Industriale dell' Universita´, Bologna, Italy bLaboratoire de Chimie Organique des Hormones, Colle`ge de France, Paris V |
| Abstract: | The absolute configuration of (+)-4-dimethylamino-2,4-diphenyl-butan-2-ol and (+)-4-piperidino-2-phenyl-pentan-2-ol, the predominant diastereomers obtained by reaction of (+)-3-dimethylamino-1,3-diphenyl-propan-1-one with MeLi and (+)-3-piperidino-1-phenyl-butan-1-one with MeMgI, respectively, was determined by chemical correlation. The relative configurations of the diastereomers afforded by such reactions were thus assigned. |
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