Thiol-ene UV-curable coatings using vegetable oil macromonomers |
| |
Authors: | Micah Black |
| |
Institution: | School of Polymers and High Performance Materials, The University of Southern Mississippi, 118 College Drive #10037, Hattiesburg, MS 39406-0001, United States |
| |
Abstract: | Allyl, acrylate, and vinyl ether derivatives of castor oil were synthesized and blended with multifunctional thiols for evaluation as thiol-ene ultraviolet (UV) curable systems. The UV cured films were characterized and evaluated via ASTM tests, gel content, and dynamic mechanical analysis (DMA) as a function of time. Fourier transform infrared spectroscopy and DMA studies established that property advancement resulted from auto-oxidation, continued thiol-ene polymerization, or a combination of both mechanisms. |
| |
Keywords: | Vegetable oil macromonomers Thiol-ene UV polymerization Coatings Castor oil Radiation cure |
本文献已被 ScienceDirect 等数据库收录! |
|