Skeletal isomerization of 1-butene on ZrO2/Al2O3 treated with sulfate ion |
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Authors: | J C Luy J C Yori A A Castro and J M Parera |
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Institution: | (1) Instituto de Investigaciones en Catálisis y Petroquímica, INCAPE, Santiago del Estero 2654, 3000 Santa Fe, Argentina |
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Abstract: | The catalytic activity for skeletal isomerization of 1-butene on ZrO2 supported on Al2O3 and doped with sulfate ion has been found to be higher than on pure ZrO2/Al2O3, Al2O3 containing sulfate ion and a commercial SiO2–Al2O3 of Ho<–13.7. Sulfate ion was capable of transforming ZrO2/Al2O3 into a solid superacid.
1- ZrO2, Al2O3 , , ZrO2, , Al2O3, , SiO2–Al2O3 Ho < –13,7. ZrO2/Al2O3 . |
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