Reaction of furfurylidene acetone with Grignard reagents |
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| Authors: | Yu N Polivin R A Karakhanov V I Kelarev B I Ugrak M E Panina |
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| Institution: | (1) I. M. Gubkin State Academy of Petroleum and Gas, Russian Academy of Sciences, 65 Leninsky prosp., 117917 Moscow, Russian Federation;(2) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation |
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| Abstract: | The interaction of furfurylidene acetone with methylmagnesium iodide and ethylmagnesium halides has been studied. In the first case 2-methyl-4-(2-furyl)-3-buten-2-ol is formed as the product of 1,2-addition (yield 73 %). In the second case 4-(2-furyl)-2-hexanone (42 %) is the result of 1,4-addition, whereas 3-methyl-5-(2-furyl)-3-heptanol (45 %) is formed by consecutive 1,2- and 1,4-addition. In all cases the products of 1,3-addition were found.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 921–923, May, 1993. |
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| Keywords: | furfurylidene acetone 2-methyl-4-(2-furyl)-3-buten-2-ol 3-methyl-5-(2-furyl)-3-heptanol 4-(2-furyl)-2-hexanone |
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