Direct synthesis of heterometallic complexes |
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Authors: | Kokozay Vladimir N. Vassilyeva Olga Yu. |
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Affiliation: | (1) Department of Inorganic Chemistry, National Taras Shevchenko University, Volodymyrska st. 64, Kyiv, 01033, Ukraine |
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Abstract: | The idea of direct synthesis of coordination compounds – use of elemental metals or their oxides as starting material – has been developed to synthesize heterometallic compounds. The advantages of this approach in obtaining polynuclear, mixed-anion and mixed-valence coordination compounds are shown, taking complexes with aminoalcohols as examples. The preparation of heterobimetallic Cu/M (Pb, Zn, Co) complexes with aminoalcohols using zerovalent copper as a starting material is presented. The main principles for the formation of heterobimetallic complexes and the most interesting crystal structures are briefly reviewed. |
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