Modeling of nonequilibrium effects in a high-velocity nitrogen-hydrogen plasma jet

A numerical simulation has been performed of a high-velocity nitrogen hydrogen plasma jet in air at atmospheric pressure including finite-rate chemical kinetics. Ions, electrons, and neutral atoms and molecules are treated as separate species in the plasma mixture. The chemical reactions considered are dissociation of molecular species, ionization of atomic species, charge exchange and dissociatioe recombination of nitrogen, and hydrogen-oxygen reactions. The calculational results show that strong departures from ionization and dissociation equilibrium develop in the downstream region as the chemical reactions freeze out at lower temperatures, in spite of the assumed chemical equilibrium at the nozzle exit. The calculations also show that ionized species are over-populated throughout the flow, while dissociated species in the core of the jet are underpopulated near the nozzle exit and become over-populated farther downstream. This initial underpopulation is due to diffusive depletion of dissociated species and enrichment of molecular species in the core of the jet.