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非水凝胶原位聚合法制备三异辛氧基镨/聚苯乙烯杂化材料
引用本文:王文,林美娟,章文贡.非水凝胶原位聚合法制备三异辛氧基镨/聚苯乙烯杂化材料[J].应用化学,2004,21(3):286-0.
作者姓名:王文  林美娟  章文贡
作者单位:福建师范大学
基金项目:福建省自然科学基金资助项目 (E0 12 0 0 0 2 )
摘    要:非水凝胶原位聚合法制备三异辛氧基镨/聚苯乙烯杂化材料

关 键 词:非水凝胶原位聚合法制备三异辛氧基镨/聚苯乙烯杂化材料  
文章编号:1000-0518(2004)03-0286-05
收稿时间:2009-06-29
修稿时间:2003年5月22日

Preparation of Praseodymium triisooctanyl oxide/PS Hybrid Materials by Non-water Gel in situ Polymerization
WANG Wen,LIN Mei-Juan,ZHANG Wen-Gong.Preparation of Praseodymium triisooctanyl oxide/PS Hybrid Materials by Non-water Gel in situ Polymerization[J].Chinese Journal of Applied Chemistry,2004,21(3):286-0.
Authors:WANG Wen  LIN Mei-Juan  ZHANG Wen-Gong
Institution:WANG Wen*,LIN Mei-Juan,ZHANG Wen-Gong
Abstract:The polystyrene(PS) hybrid materials were obtained by the in situ polymerization from a gel by mixing of styrene and praseodymium triisooctanyl oxide Pr(i-C 8) in the absence of water. The materials have been characterized by FT-TR, TG-DTA, DMTA, ESEM, UV and fluorescence spectrometry. The process avoids the aggregation of rare earth in the materials. The introduction of praseodymium triisooctanyl oxide improves the heat resistance and fluorescence intensity of the hybrid. The materials with 4.0%(mass fraction) praseodymium have better transparency. ESEM reveals the crosslinked network structure of PS hybrid material.
Keywords:praseodymium triisooctanyl oxide  polystyrene  hybrid materials  non-water insitu polymerization
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