Reactivity and stereoselectivity of the Diels-Alder reaction using cyclic dienophiles and siloxyaminobutadienes |
| |
Authors: | Toshiyuki OhfusaAtsushi Nishida |
| |
Institution: | Graduate School of Pharmaceutical Sciences, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan |
| |
Abstract: | Several bicyclic compounds were synthesized by the Diels-Alder reaction using aminodiene and a cyclic dienophile. The stereochemistries of the obtained adducts were determined by X-ray crystallography or NMR analysis. The stereoselectivity of this Diels-Alder reaction was based on the interaction of molecular orbitals between the diene and dienophile. The reactivities of these Diels-Alder reactions were estimated, and the generality of this reaction is discussed. |
| |
Keywords: | Diels-Alder reaction Siloxyaminobutadiene Cyclic dienophile Stereoselectivity Reactivity |
本文献已被 ScienceDirect 等数据库收录! |