Azodioxy-carbonyl compounds by oxidation of cyclic imines with m-CPBA |
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| Authors: | Serena PerroneTullio Pilati Francesca RosatoAntonio Salomone Valeria VidettaLuigino Troisi |
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| Affiliation: | a Dipartimento di Scienze e Tecnologie Biologiche ed Ambientali, University of Salento, Via Prov.le Lecce-Monteroni, 73100 Lecce, Italy
b C.N.R. ‘Institute of Molecular science and Technology’, Via C. Golgi 19, 20133 Milano, Italy |
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| Abstract: | This article reports a simple and efficient synthesis of C-nitroso compounds (azodioxy esters or ketones and oximes) through a double oxidation of cyclic imines (4,5-dihydrooxazoles and 3,4-dihydro-2H-pyrroles) with m-CPBA. C-Nitroso derivatives seem to be potential donors of nitric oxide, one of the most powerful biological messenger. |
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| Keywords: | Imines Oxaziridines Azodioxy Oximes C-Nitroso compounds |
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