Unique chemoselective Clauson-Kass reaction of substituted aniline catalyzed by MgI2 etherate |
| |
| Authors: | Xingxian Zhang Junchen Shi |
| |
| Institution: | College of Pharmaceutical Sciences, Zhejiang University of Technology, Hangzhou, Zhejiang 310032, PR China |
| |
| Abstract: | Clauson-Kass reaction of various substituted aniline, primary aryl amide, and sufonyl amide with 2,5-dimethoxytetrahydrofuran was realized in the presence of 10 mol % of MgI2 etherate in a mild, efficient, and highly chemoselective manner. Iodide counterion and solvents (i.e., MeCN) played the critical roles for the unique reactivity of this catalytic system. |
| |
| Keywords: | Chemoselective Dimethoxytetrahydrofuran Pyrrole Clauson-Kaas reaction MgI2 etherate |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
