Stereochemistry of the hydrogenolysis of 1,2-disubstituted ferrocenes in acid media |
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| Authors: | V. I. Sokolov T. M. Filippova N. S. Khrushcheva L. L. Troitskaya |
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| Affiliation: | (1) A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Conclusions The catalytic hydrogenolysis of enantioimeric 1,2-disubstituted ferrocenes in H2 at 1 atra over Pd/C in CF3]CO2H at 50°C leads predominantly to the trans isomers of the corresponding 1,2-disubstituted cyclopentanes; optical activity is lost.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2600–2603, November, 1986. |
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