Dicarbollide complexes of rhodium and ruthenium |
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| Authors: | Allen R Siedle |
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| Institution: | Inorganic Chemistry Section, National Bureau of Standards, Washington, D.C. 20234 U.S.A.;Department of Chemistry, Indiana University, Bloomington, Indiana 47401 U.S.A. |
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| Abstract: | The 7,8-B9C2H112- ion reacts with (Ph3P)2Rh(CO)Cl to form (B9C2H11)-Rh(Cl)(Ph3P)2. This rhodacarborane reacts with NaBPh4 to produce (B9C2H11-Rh(Ph3P)(Ph4B). The new metallocarboranes (B9C2H11)Rh(Ph3P)(C6H6)]2 and (B9C2H11)Rh(H)(Ph3P) were obtained from the reaction of B9C2H112- and (Ph3P)3RhCl. The ruthenacarboranes (B9C2H11)Ru(CO)(Ph3P)2 and (B9C2H11-Ru(CO)3 · 0.5C6H6 were prepared from (Ph3P)Ru(CO)2Cl2 and Ru(CO)3Cl2]2 respectively. |
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