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Optical properties of Eu:CsGd2F7 downconversion phosphor
Authors:Miros?aw Karbowiak  Agnieszka Mech
Institution:a Faculty of Chemistry, University of Wroc?aw, ul. F. Joliot-Curie 14, 50-383 Wroc?aw, Poland
b W. Trzebiatowski Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 1410, 50-950 Wroc?aw, Poland
Abstract:Luminescence spectra and excitation spectra in 150-420 nm spectral region have been recorded at room temperature for polycrystalline sample of (0.5%)Eu3+:CsGd2F7. The relatively intense emission has been observed from 5D3, 5D2 and 5D1 levels. Emission and excitation spectra prove that the excitation energy is efficiently transferred from the 6GJ and 6IJ levels of Gd3+ ions to Eu3+ ions. The visible quantum cutting via downconversion has been detected, with efficiency of the cross-relaxation step of ∼50%.
Keywords:Downconversion  Quantum cutting  Vacuum ultraviolet  Phosphor  CsGd2F7
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